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Preparation and application of metal-modified biochar in the purification of micro-polystyrene polluted aqueous environment
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Researchers developed iron-modified biochar, a charcoal-like material, that can remove over 96% of polystyrene microplastics from water under controlled lab conditions. The material worked well in tap water and lake water but was less effective in heavily polluted water with high levels of organic matter. This type of low-cost water treatment technology could help reduce the amount of microplastics in drinking water, though more work is needed to apply it at larger scales.
Microplastics (MPs) have already spread across the globe and have been found in drinking water and human tissues. This may pose severe threats to human health and water environment. Therefore, this study accurately evaluated the removal effect of metal-modified biochar on polystyrene microplastics (PS-MPs) (1.0 μm) in the water environment using a high-throughput fluorescence quantification method. The results indicated that Fe-modified biochar (FeBC) and Fe/Zn-modified biochar (Fe/ZnBC) had good removal efficiencies for PS-MPs under the dosage of 3 g/L, which were 96.24% and 84.77%, respectively. Although pore effects were observed (such as "stuck", "trapped"), the electrostatic interaction was considered the main mechanism for the adsorption of PS-MPs on metal-modified biochar, whereas the formation of metal-O-PS-MPs may also contribute to the adsorption process. The removal efficiency of PS-MPs by FeBC was significantly reduced under alkaline conditions (pH = 9 and 11) or in the presence of weak acid ions (PO, CO, HCO). A removal efficiency of 72.39% and 78.33% of PS-MPs was achieved from tap water (TW) and lake water (LW) using FeBC when the initial concentration was 20 mg/L. However, FeBC had no removal effect on PS-MPs in biogas slurry (BS) and brewing wastewater (BW) due to the direct competitive adsorption of high concentrations of chemical oxygen demand (COD). The findings of this study highlighted that metal-modified biochar had a potential application in purifying tap water or lake water which contaminated by MPs.
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This review combined 12 lab studies on using charcoal-like materials, biochar and activated carbon, to remove tiny plastic particles from water. Versions treated with iron compounds removed over 90% of particles in lab tests, but most experiments used artificial water and clean plastic samples, not real-world conditions.
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Tiny plastic particles are showing up everywhere in our water, and current treatment plants can only filter out 40-78% of them, meaning the rest ends up in our environment and potentially our bodies. This review paper highlights biochar—a charcoal-like material made from plant waste—as a cheap, eco-friendly filter that can be specially engineered to capture up to 99% of microplastics from water. While promising, scientists still need to standardize these methods and test them at larger scales before this becomes a widespread solution for cleaner drinking water.
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Researchers developed magnesium- and zinc-modified magnetic biochars that achieved over 94% removal efficiency for polystyrene microplastics from water, with performance enhanced by the metal modifications. The modified biochars also showed effectiveness in thermally degrading the captured microplastics, offering a potential two-step approach for microplastic removal and destruction in water treatment.
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