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Transport of polypropylene, polyvinyl chloride, polyethylene terephthalate and polymethyl methacrylate microplastics in porous media under gradient ionic strength
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Researchers used column experiments to study how four types of microplastics — polypropylene, PVC, PET, and PMMA — move through soil-like porous media under different salt concentrations. They found that increasing salinity reduces microplastic mobility by causing particles to stick to sand surfaces, which has implications for predicting how far microplastics can travel through soils to reach groundwater.
In this work, column experiments were applied to investigate the transport of four kinds of microplastics (MPs) under a series of ionic strength (IS) conditions. Under 0.1 mM IS, PMMA MPs showed the highest mobility, as well as the PET MPs showed the lowest mobility. With the IS increased, the transport of all kinds of MPs in porous media was generally reduced to the minimum. The transport reducing efficiency of PMMA MPs and PET MPs was lower than that of the PVC MPs and PP MPs. It was found that both the hydro-chemical conditions and basic properties showed combined effect on MPs transport in porous media. The DLVO results were well used to describe the deposition of MPs onto sand surface and excavate the transport behaviors of MPs. The one-site kinetic deposition model was successfully conducted to fit the observed breakthrough curves. Findings from this study elucidated the key factors controlling the MPs transport in porous media, contributing to the prediction and assessment of the environmental risks of MPs.
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Researchers studied how polyethylene microplastics move through water-saturated sand and gravel, testing the effects of particle size, water chemistry, and flow speed. They found that smaller microplastics traveled farther through the porous material, while higher salt concentrations and lower flow rates increased particle retention. The findings help explain how microplastics may spread through groundwater systems under real-world conditions.
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Experiments showed that both water flow speed and salt concentration work together to control how microplastic particles stick to and move through sand and soil. Understanding these combined effects is important for predicting how microplastics travel through groundwater and contaminate water supplies.
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Laboratory sand column experiments showed that polyethylene microplastic transport is inhibited by high ionic strength (as it reduces the repulsion between particles and sand grains) but enhanced by fulvic acid (which increases surface charge repulsion). The study provides mechanistic data for predicting how microplastics move through soils under different environmental chemical conditions.
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