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Mini Review on Recent Advances of the Adsorption Mechanism Between Microplastics and Emerging Contaminants for Conservation of Water

International Journal of Conservation Science 2023 3 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count.
Mohamed Syazwan Osman, Muhammad Ikhwan Nizam, Sharifah Nurul Ain SYED MOHAMAD SHUKRI, Syahirah MOHAMAD SHUKRI

Summary

This mini-review examines the adsorption mechanisms between microplastics and emerging contaminants such as pharmaceuticals, highlighting how physicochemical properties like hydrophobicity and pH influence pollutant uptake onto different polymer types. The review synthesizes recent advances relevant to understanding how microplastics act as vectors for pharmaceutical contaminants in aquatic environments.

Polymers

Pharmaceuticals and microplastics have long been identified as water pollutants. Pollutants, including pharmaceutical compounds, have been shown to be transported by microplastics (MPs). In this mini-review, adsorption mechanism between microplastics and emerging contaminants were highlighted. Polyethylene is a non-polar, semi-cystalline microplastic with a density of 240 to 244 kg/m3. Besides, Ibuprofen adsorption onto microplastics is pH dependent. Non-polar or neutral compounds that are homogeneous and extremely hydrophobic in nature interact with non-polar and weakly polar plastics such as Polypropylene and Polyethylene. Furthermore, Molecular dynamic (MD) simulation can be employed to study the mechanism of interaction between MPs and contaminants. As a result, some studies show a complex interaction between polyethylene (PE) and certain contaminants, with no significant differences in adsorption energies, but sulfamethazine molecules effectively adsorbed on the MPs surface. In summary, this mini review shed lights on the insights of adsorption mechanism between these compounds.

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