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Interfacial interactions of polyethylene terephthalate microplastics and malachite green, tetracycline in aqueous environments
Summary
This study examined how UV aging changes the surface properties of polyethylene terephthalate microplastics and how those changes affect their ability to adsorb pollutants like malachite green and tetracycline. Researchers found that aged microplastics showed increased adsorption capacity, and the co-presence of copper ions further influenced these interactions in aqueous environments.
Polyethylene terephthalate microplastics (PET-MPs) are one of pivotal nondegradable emerging pollutant. Here the variation of the surface physicochemical characteristics of PET-MPs with UV irradiation aging and the adsorption behaviors of PET-MPs in malachite green (MG), tetracycline (TC) solution and the effect of coexisting Cu(II) were comparatively investigated. The yellowing, weakened hydrophobicity, and increased surface negative charge, crystallinity degree and oxygen-containing functional groups were manifested specifically by the aged PET-MPs. Different from the single system, the hydrophobic interaction and metal ion bridging complexation dominated the adsorption of MG and TC, respectively, in the binary solution. While in the ternary solution, cationic ion competition of Cu(II) with MG decreased its capture, and the formation of PET-Cu(II)-TC ternary complexes promoted TC adsorption. Moreover, PET-MPs could serve as an efficient vector for MG and TC in MG/TC/Cu(II) ternary system, indicating PET-MPs tend to carry more varieties in the complex environment, that may increase the environmental risk of PET-MPs.