We can't find the internet
Attempting to reconnect
Something went wrong!
Hang in there while we get back on track
Effect of chlorination and ultraviolet on the adsorption of pefloxacin on polystyrene and polyvinyl chloride
Summary
Researchers found that water treatment processes like chlorination and UV sterilization actually change the surface properties of microplastics, making them better at absorbing the antibiotic pefloxacin. Chlorination had a stronger effect than UV treatment, increasing the microplastics' ability to carry this pharmaceutical pollutant. This is concerning because it means standard water treatment could unintentionally make microplastics more effective at transporting drugs and other chemicals into drinking water.
During the water treatment process, chlorination and ultraviolet (UV) sterilization can modify microplastics (MPs) and alter their physicochemical properties, causing various changes between MPs and other pollutants. In this study, the impact of chlorination and UV modification on the physicochemical properties of polystyrene (PS) and polyvinyl chloride (PVC) were investigated, and the adsorption behavior of pefloxacin (PEF) before and after modification was examined. The effect of pH, ionic strength, dissolved organic matter, heavy metal ions and other water environmental conditions on adsorption behavior was revealed. The results showed that PS had a higher adsorption capacity of PEF than PVC, and the modification increased the presence of O-containing functional groups in the MPs, thereby enhancing the adsorption capacity of both materials. Chlorination had a more significant impact on the physicochemical properties of MPs compared to UV irradiation within the same time period, leading to better adsorption performance of chlorination. The optimal pH for adsorption was found to be 6, and NaCl, sodium alginate and Cu would inhibit adsorption to varying degrees, among which the inhibition caused by pH was the strongest. Chlorination and UV modification would weaken the inhibitory effect of environmental factors on the adsorption of PEF by MPs. The main mechanisms of adsorption involved electrostatic interaction and hydrogen bonding. The study clarified the effects of modification on the physicochemical properties of MPs, providing reference for subsequent biotoxicity analysis and environmental protection studies.
Sign in to start a discussion.
More Papers Like This
Chlorination-improved adsorption capacity of microplastics for antibiotics: A combined experimental and molecular mechanism investigation
Researchers found that when microplastics go through chlorine disinfection in water treatment plants, they become better at absorbing antibiotics like tetracycline. Chlorination changes the surface of polystyrene microplastics, making them stickier for these drugs through stronger chemical bonding. This means treated wastewater may contain microplastics loaded with antibiotics, potentially increasing health risks when released into the environment.
The impact of chlorination on the tetracycline sorption behavior of microplastics in aqueous solution
Researchers found that chlorination, a common disinfection step in wastewater treatment, alters the surface chemistry of microplastics and changes their capacity to adsorb tetracycline antibiotics, with chlorinated microplastics showing modified sorption behavior that affects their role as antibiotic carriers.
Adsorption of levofloxacin by ultraviolet aging microplastics
Researchers studied how ultraviolet aging changes the ability of common microplastics to adsorb the antibiotic levofloxacin. The study found that UV-aged polystyrene, polyamide, and polyethylene microplastics all showed significantly enhanced adsorption capacity compared to their unaged counterparts, suggesting that weathered microplastics in the environment may carry higher pollutant loads.
Transformation of dissolved organic matter leached from biodegradable and conventional microplastics under UV/chlorine treatment and the subsequent effect on contaminant removal
This study examined how dissolved chemicals leaching from both biodegradable and conventional microplastics behave during UV/chlorine water treatment. The treatment changed the chemical properties of the leached substances and actually inhibited the breakdown of a common antibiotic pollutant. The findings suggest that microplastic-derived chemicals in water could interfere with standard water purification processes, potentially reducing their effectiveness.
Modifications to sorption and sinking capability of microplastics after chlorination
Researchers found that chlorination disinfection at both low and high doses modified the surface chemistry of PE, PET, PS, and PVC microplastics, increasing surface area and reducing hydrophobicity while weakening their capacity to sorb contaminants like ciprofloxacin. The study concluded that chlorination generally reduces the role of microplastics as transport vectors for organic pollutants, though effects on buoyancy varied by polymer type.