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Magnetic Harvesting and Degradation of Microplastics using Iron Oxide Nanoflowers prepared by a Scaled-up Procedure
Summary
Researchers developed magnetic iron oxide "nanoflowers" that can capture microplastics from water using a magnet, removing up to 1,000 milligrams of plastic per gram of nanoflowers. After capture, the same nanoflowers can break down the plastics through a chemical reaction that destroys up to 80% of the material -- offering a promising two-step approach for cleaning microplastic-contaminated water.
• Iron oxide nanoflowers (NFs) were synthesized at gram-scale by the polyol method. • The scaled synthesis of NFs exhibited a 91 % mean reproducibility. • Magnetic harvesting of microplastics (MPs) led to a removal capacity of 1000 mg/g NF . • NFs-catalyzed MPs degradation yielded up to 80% mineralization. • NFs-magnetic induction heating improved MPs degradation reaction. Addressing the ecological risks and human health threats posed by emerging contaminants requires the development of reproducible and scalable materials and technologies. In this context, the performance of multicore flower-shaped nanoparticles (NFs) with approximately 40 nm diameters was assessed for extracting and degrading polyethylene microplastics from cosmetics in water samples. These NFs, exhibiting cooperative magnetic behavior and high magnetic moment per particle, were scaled to grams of product in a larger reactor (1 L), yielding a 91 % mean reproducibility for structural, colloidal and magnetic properties. The NFs were directly attached to microplastic surfaces via ultrasonic treatment and separated using a permanent magnet, demonstrating removal capacities of up to 1000 mg MP /g NF under optimal conditions (pH 7, 10 mg NFs, 30 min, field strength 320 kA/m). Subsequently, microplastics in aqueous suspensions were hydrolyzed at 150 °C followed by mineralization through a Fenton-like reaction catalyzed by the NFs where reactive oxygen species produced, in the presence of H 2 O 2 , break the organic molecules. Mineralization yields ranged from 20 % to 75 % at 25 and 90 °C, respectively, with a further increase to 78 % achieved under an alternating magnetic field (60 mT, 100 kHz), obviating the need for high temperatures. These results highlight the potential of NFs and associated technologies in effectively addressing the challenges associated with emerging contaminants, offering promising avenues for environmental remediation and human health protection.