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The Impact of Virgin and Aged Microstructured Plastics on Proteins: The Case of Hemoglobin Adsorption and Oxygenation
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This study compared the effects of virgin and aged microstructured plastics on primary productivity in aquatic environments, finding that weathered plastics had greater inhibitory effects on algal growth than pristine particles. Aging altered particle surface chemistry in ways that increased toxicity to photosynthetic organisms.
Plastic particles, particularly micro- and nanoparticles, are emerging pollutants due to the ever-growing amount of plastics produced across a wide variety of sectors. When plastic particles enter a biological medium, they become surrounded by a corona, giving them their biological identity and determining their interactions in the living environment and their biological effects. Here, we studied the interactions of microstructured plastics with hemoglobin (Hb). Virgin polyethylene microparticles (PEMPs) and polypropylene microparticles (PPMPs) as well as heat- or irradiation-aged microparticles (ag-PEMPs and ag-PPMPs) were used to quantify Hb adsorption. Polypropylene filters (PP-filters) were used to measure the oxygenation of adsorbed Hb. Microstructured plastics were characterized using optical microscopy, SAXS, ATR-FTIR, XPS, and Raman spectroscopy. Adsorption isotherms showed that the Hb corona thickness is larger on PPMPs than on PEMPs and Hb has a higher affinity for PPMPs than for PEMPs. Hb had a lower affinity for ag-PEMPs and ag-PPMPs, but they can be adsorbed in larger amounts. The presence of partial charges on the plastic surface and the oxidation rate of microplastics may explain these differences. Tonometry experiments using an original method, the diffuse reflection of light, showed that adsorbed Hb on PP-filters retains its cooperativity, but its affinity for O2 decreases significantly.
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Researchers found that microalgal biofouling caused more significant aging and surface degradation of microplastics compared to river microbial biofouling over a 30-day period. The study suggests that algae-induced aging substantially enhances the ability of polyethylene and PVC microplastics to adsorb organic pollutants like bisphenol analogues, increasing their potential to transport contaminants in the environment.
Interactions between polypropylene microplastics (PP-MPs) and humic acid influenced by aging of MPs
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Researchers examined how aging affects polypropylene microplastic interactions with humic acid, finding that aged microplastics with increased surface oxygen groups showed stronger adsorption of humic acid compared to pristine particles, altering their environmental behavior.
Exploring Different Toxic Effects of UV-Aged and Bio-Aged Microplastics on Growth and Oxidative Stress of Escherichia coli
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This study compared the toxic effects of UV-aged and bio-aged microplastics on aquatic microorganisms, finding that different aging processes alter MP surface properties in distinct ways that produce different patterns of toxicity to bacteria and algae in aquatic environments.
Laboratory simulation of microplastics weathering and its adsorption behaviors in an aqueous environment: A systematic review
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UV photo-oxidation and physical abrasion are the most practical laboratory methods for simulating microplastic weathering; aging increases surface area and oxygen-containing functional groups, altering pollutant adsorption behavior and potentially increasing environmental risks.
Photoaging mechanisms of microplastics mediated by dissolved organic matter in an iron-rich aquatic environment
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Researchers investigated how dissolved organic matter and iron mediate the photoaging of PVC and PET microplastics, finding that humic acid and iron accelerate surface degradation and alter the environmental behavior and risks of aged microplastics.
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