Surface enhanced raman spectroscopy based sensitive and onsite detection of microplastics in water utilizing silver nanoparticles and nanodendrites

Plastics, of the order of microns in size, being not visible to the naked eye, are one of the significant contributors to pollution in the environment. Thus, the detection of micron-sized plastics (microplastics (MPs)) is crucial because of its hazardous toxic effects on our surroundings. In this work, we have proposed a quick and on-site detection of MPs, such as, polyvinyl chloride (PVC), polyvinyl alcohol (PVA) and polystyrene (PS) at ultra trace level using surface-enhanced Raman spectroscopy (SERS). To detect and analyse the spectra, two different nanostructures, such as, spherical shaped Ag nanoparticles (NPs), and shape anisotropic Ag nano-dendrites (NDs) were utilised to acquire the SERS spectra. A comprehensive analysis was further performed to check and investigate the amount of enhancements due to the mentioned nanostructures. We observed the Ag NDs exhibited amplified signal intensity compared to the Ag NPs due to the shape anisotropy leading to the surface charge confinement effect to create highly dense hotspots. However, the spherical shaped polystyrene beads of micron size exhibited better enhancement in Raman signal intensity when mixed with Ag NPs due to increased surface adsorption with the NPs. Therefore, the comparative study emphasizes the ability of using solution-based nanostructure as SERS for the onsite detection of microplastics having diverge size range at low concentration.