We can't find the internet
Attempting to reconnect
Something went wrong!
Hang in there while we get back on track
Upconversion Phosphor-Driven Photodegradation of Plastics
Summary
Researchers developed a novel approach to accelerate plastic degradation using upconversion phosphors that convert visible light into ultraviolet radiation. When added to plastics, these materials dramatically increased the rate at which common plastics like polyethylene and polypropylene broke down under sunlight. The study suggests this technology could help address plastic waste accumulation in the environment by making plastics degrade faster naturally.
Plastic waste poses a profound threat to ecosystems and human health, necessitating novel strategies for effective degradation in nature. Here, we present a novel approach utilizing upconversion phosphors as additives to significantly accelerate plastic photodegradation in nature via enhancing ultraviolet (UV) radiation. Pr-doped Li2CaGeO4 (LCGO:Pr) upconversion phosphors readily converting blue light into deep-UV radiation, dramatically improve photodegradation rates for polyethylene (PE) and polyethylene terephthalate (PET) microplastics. In situ spectroscopic studies show that upconversion fluorescence initiates the photophysical cleavage of C-C and C-O bonds in the backbones of PE and PET, resulting in plastic degradation. Moreover, incorporating LCGO:Pr into polypropylene (PP) sheets realizes markedly enhanced photodamage, with the cracking area increasing by nearly 38-fold under simulated sunlight for 10 days. This underscores the potential of employing this approach for the construction of light-driven destructible polymers. Further optimization and exploration of material compatibility hold promise for developing sustainable photodegradable plastics.