Efficient removal performance of polystyrene microplastics from strongly acidic solutions by two functionalized nanosized biochars derived from low-cost sustainable sources

Microplastic pollution in aquatic systems and other environments has garnered significant concern due to its persistence, widespread environmental migration, and detrimental impact on entire ecosystems. Such pollution type poses severe threats to human life quality, as well as flora and fauna. In response to this pressing global issue, the current research explores a simple, sustainable, and cost-effective solution by employing two newly modified nanobiochar materials with oxalic acid, for the adsorptive removing of polystyrene microplastics (PSMPs) from aquatic systems. The two nanobiochars were derived from sustainable and low-cost feedstocks, specifically pineapple and artichoke wastes via pyrolysis at 300 °C and 350 °C, yielding NBP and NBA, respectively. These were subsequently modified with oxalic acid (OA) to create OA@NBP and OA@NBA nanobiosorbents. The EDX analysis confirmed the primary elemental composition of carbon, oxygen, nitrogen, calcium, and magnesium. TEM analysis revealed distinct differences in particle size and morphology of OA@NBA which displayed small particles ranging from 9.81 to 16.15 nm, while OA@NBP exhibited larger particles with size ranging from 68.86 to 105.12 nm, highlighting their structural differences. OA@NBP and OA@NBA nanobiosorbents were evaluated in PSMPs removing from aquatic systems providing the optimum conditions 30-50 mg nanobiosorbent, 40 min time and pH 2.0. The adsorption and binding mechanisms were best fitted to pseudo-second-order kinetics and Langmuir-Freundlich models. Thermodynamic analysis revealed that the adsorption process was non-spontaneous and endothermic. The loaded PSMPs on OA@NBA and OA@NBP nanobiosorbents were successfully regenerated and successively used to remove PSMPs with 86.8 % and 89.5 %, respectively, after the first regeneration step. Additionally, the two nanobiosorbents demonstrated excellent PSMPs removal efficiencies in simulated seawater samples adjusted to pH 2.0, achieving removal rates of 93.4 % (OA@NBA) and 87.4 % (OA@NBP). Therefore, the characterized PSMPs removal performance at pH 2.0 can afford a good avenue for potential application of the two explored nanobiosorbents in effective removal of PSMPs pollutant from other acidic industrial wastewater matrices.