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Hierarchical Interlayer Design for Wheat Straw-Based Straws: Exceptional Mechanical Robustness and In-Situ Capture of Micro/Nano Plastics.

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Researchers engineered a biodegradable drinking straw from wheat straw using coatings that improved strength, water resistance, and thermal stability. In lab testing, the straw's outer coating captured up to about 36% of negatively charged microplastics and nanoplastics from water, based on turbidity measurements.

Polymers

Biodegradable drinking straws derived from agricultural residues are limited by poor wet durability, weak interfacial bonding, and insufficient functionality. Herein, wheat straw was converted into a biodegradable straw for potential food-contact applications through hierarchical interface engineering comprising stearic acid hydrophobization, a poly(lactic acid)/cellulose nanocrystal-thioctic acid (PLA/CNC-TA) reinforcing interlayer, and a polydopamine (PDA) outer layer. Stearic acid reduced water uptake, whereas CNC-TA enhanced interfacial compatibility and stress transfer through hydrogen bonding and thioctic-acid-associated interactions. The optimized PP4/WS-SA straw achieved a tensile strength of 64.8 MPa and retained approximately 46 MPa after water exposure. PDA introduced catechol and amine groups, enabling partial capture of negatively charged micro-/nano plastics (MNP), with a maximum turbidity-based removal efficiency of approximately 36%. The straw also exhibited improved thermal stability, food-simulant migration values below the tested limits, and progressive soil degradation, demonstrating a promising value-added application for agricultural-residue tableware.

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