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Caught in the net: A quaternized wood fiber/chitin nanofibril hydrogel trap for polystyrene nanoplastics.

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Scientists created a sponge-like material made from wood and shellfish waste that can soak up huge amounts of nanoplastics, tiny plastic particles too small to see that have been showing up in our water, food, and even bloodstreams. Unlike many plastic-cleanup materials, this one is made entirely from natural, biodegradable ingredients, works well even in real-world water with other minerals present, and can be reused over 30 times before safely breaking down in soil. While this is still lab-stage research, it points toward a practical, eco-friendly way to filter nanoplastics out of water before they reach our bodies.

Polymers

Nanoplastics pollution requires sustainable remediation technologies aligned with green chemistry and circular economy principles. Here, we report a fully biomass-derived, hierarchically structured hydrogel adsorbent for efficient removal of polystyrene nanoplastics (PSNPs). The hydrogel was fabricated by integrating quaternized wood fibers (QWF), derived from lignocellulosic biomass, with chitin nanofibrils (ChNFs), forming an interconnected micro-nano hierarchical porous network. Structural integrity was achieved through physical entanglement and hydrogen bonding, without toxic chemical crosslinkers during hydrogel formation. The cationic hierarchical architecture provided abundant electrostatic anchoring sites, internal diffusion pathways, and excellent mechanical stability, enabling a high adsorption capacity of 1940 mg g (calculated q: 2109 mg g) with rapid adsorption kinetics. The hydrogel also maintained strong performance (>750 mg g) in complex real-water matrices containing competing ions. Moreover, the adsorbent exhibited excellent reusability, retaining over 98% removal efficiency after 30 cycles via acid-assisted mechanical compression. The pristine hydrogel underwent complete biodegradation within 23 days in soil (ISO 17556), whereas the spent adsorbent collected after PSNP capture showed delayed but complete biodegradation within approximately 40 days. This work demonstrates a potentially scalable biomass-derived adsorbent matrix for environmentally responsible nanoplastics remediation. Overall, the design reconciles adsorption performance, regenerability, and end-of-life management in one practical platform.

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