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Synthesis of metal organic framework-based hydrogel for microplastics removal from aquatic environments

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Scientists have created a sponge-like material that can filter out up to 98% of microplastics from wastewater, including the kind released when we wash synthetic clothing, one of the biggest sources of microplastic pollution. Since microplastics have been found in our food, water, and even our bodies, this reusable filter could help stop plastic particles from entering our environment (and eventually our bodies) in the first place. While still in the research phase, this technology offers a promising, practical tool for tackling microplastic pollution at its source, like laundry systems and wastewater treatment plants.

Polymers
Study Type Environmental

Microplastics (MPs) pollution has emerged as a pressing global environmental problem. Current research in this field remains exploratory because there is a lack of standards, methods, and policies for the detection, removal, and regulation of MPs discharge. In this study, a series of metal-organic framework (MOFs)-incorporated hydrogels was successfully fabricated via a photo-initiated cross-linking strategy, offering a facile and efficient preparation approach applicable to the removal of diverse MPs types. Among them, ZIF-8.1@H6mg exhibited the highest MPs removal efficiencies, achieving up to 97% for polyethylene terephthalate (PET) and 98% for polyethylene (PE) in laundry wastewater, one of the main sources of MPs pollution. The material demonstrated excellent recyclability, with MPs removal efficiency only slightly decreasing to 96% after six reuse cycles. It maintained stable operation for approximately 4 h, and pre-treatment with backwashing further enhanced long-term filtration performance. Comprehensive characterization of the ZIF-8 hydrogel composites suggests that their interpenetrating network structures, zeta potential, and surface functional groups contributed to their superior performance. These findings highlight the potential of ZIF-based hydrogels as sustainable and effective materials for mitigating the growing threat of MPs pollution.

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