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Converting polyethylene-based fishing net waste into ethylene via catalytic pyrolysis over oyster shell waste

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Scientists found a way to turn old fishing nets, a major source of ocean plastic pollution and microplastics, into ethylene, the building block for making new plastic. By combining discarded oyster shells and carbon dioxide as catalysts, they boosted the process's efficiency, offering a promising way to recycle ocean waste instead of burning or dumping it.

Fishing net waste (FNW) is one of the most persistent and harmful marine plastic pollutants. Yet most recovered FNW is landfilled or incinerated, causing secondary environmental pollution. Herein, polyethylene (PE)-based FNW was converted into ethylene, the monomeric building block of PE, via CO-assisted pyrolysis. Conventional pyrolysis mainly yielded waxy condensable products. Extending volatile residence time at elevated temperature promoted secondary cracking toward lighter products, more markedly under CO, yet ethylene remained limited. Oyster shell waste (OSW, 98.3 wt% CaCO), another abundant marine waste, was therefore employed as a Ca-rich catalyst in the downstream zone, promoting cracking of condensable hydrocarbons into light gases. Combining OSW and CO increased the ethylene yield to 24.37 wt%. The higher CO yield under CO than N (2.24 vs. 0.45 wt%) is consistent with CO-mediated gas-phase reactions of OSW-generated intermediates. Superior ethylene production despite less CaO formation indicates that the enhancement is most consistent with CO participation rather than catalyst basicity. Techno-environmental assessment estimated gross benefits of 1.05 t CO-eq (0.28 t as permanent fossil displacement) and US$442 per tonne of FNW, excluding process burdens. Overall, this closed-loop strategy co-utilizes two marine wastes and CO to recover ethylene for virgin PE production while mitigating disposal-derived pollution.

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