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Upcycling of polyethylene terephthalate plastic waste to microporous carbon structure for energy storage

Journal of Environmental Issues and Climate Change 2020 43 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count.
Arash Mirjalili, Bo Dong, Pedro Peña, Cengiz S. Ozkan, Mihrimah Ozkan

Summary

This study upcycled waste polyethylene terephthalate bottles into electrochemical carbon material using electrospinning, producing a mixed amorphous carbon and reduced graphene oxide material suitable for double-layer supercapacitors. Electrochemical characterization confirmed combined double-layer and pseudo-capacitance behavior with a self-strengthening effect, demonstrating an environmentally and economically advantageous pathway for PET waste valorization.

Polymers

Abstract Plastic pollution and its harmful effects on the earth ecosystem, which inevitably affect quality of life, have brought attention to the frontiers of research society. Among plastics, polyethylene terephthalate (PET) is used on a massive scale in various sectors of industry, including the automobile, textile, and packaging. Utilizing an electrospinning fiber production technique, we have successfully upcycled PET waste bottle into electrochemical active carbon material that functions as a double‐layer supercapacitor substance. Our detailed electrochemical and analytical characterization revealed that the generated carbon substance is a mixture of amorphous carbon and reduced graphene oxide with relatively high surface area. The electrochemical characterization of the as‐prepared material consisting of cyclic voltammetry, galvanostatic cycling with potential limitations, and electrochemical impedance spectroscopy analyses revealed that the generated medium has combined characteristics of both double‐layer and redox reaction pseudo‐capacitance with self‐strengthening effect along cycling. We believe that the proposed process is scalable with environmental and economic advantages and this study could present opportunities for future research and development.

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