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Photocatalytic Degradation of Microplastics in Aquatic Environments: Materials, Mechanisms, Practical Challenges, and Future Perspectives
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This review examines how light-activated materials called photocatalysts can break down microplastics in water into harmless byproducts using sunlight or UV light. While still facing challenges with incomplete breakdown and variable sunlight conditions, this technology offers a promising way to reduce microplastic contamination in water sources that affect human health.
Due to its persistence and potential negative effects on ecosystems and human health, microplastic pollution in aquatic environments has become a major worldwide concern. Photocatalytic degradation is a sustainable manner to degrade microplastics to non-toxic by-products. In this review, comprehensive discussion focuses on the synergistic effects of various photocatalytic materials including TiO2, ZnO, WO3, graphene oxide, and metal–organic frameworks for producing heterojunctions and involving multidimensional nanostructures. Such mechanisms can include the generation of reactive oxygen species and polymer chain scission, which can lead to microplastic breakdown and mineralization. The advancements of material modifications in the (nano)structure of photocatalysts, doping, and heterojunction formation methods to promote UV and visible light-driven photocatalytic activity is discussed in this paper. Reactor designs, operational parameters, and scalability for practical applications are also reviewed. Photocatalytic systems have shown a lot of development but are hampered by shortcomings which include a lack of complete mineralization and production of intermediary secondary products; variability in performance due to the fluctuation in the intensity of solar light, limited UV light, and environmental conditions such as weather and the diurnal cycle. Future research involving multifunctional, environmentally benign photocatalytic techniques—e.g., doped composites or composite-based catalysts that involve adsorption, photocatalysis, and magnetic retrieval—are proposed to focus on the mechanism of utilizing light effectively and the environmental safety, which are necessary for successful operational and industrial-scale remediation.
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This review paper summarizes existing research on using light-activated materials (photocatalysts) to break down microplastics in water. It compares five material types tested in lab settings, noting some achieved high breakdown rates under UV or visible light, while identifying unresolved challenges like treating certain plastic types and assessing long-term environmental safety.
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