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Alkoxy-silyl Induced Agglomeration: A New Approach for the Sustainable Removal of Microplastic from Aquatic Systems

Journal of Polymers and the Environment 2018 122 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count.
Adrian Frank Herbort, Michael Sturm, S. Fiedler, Golnar Abkai, Katrin Schuhen

Summary

A sol-gel agglomeration technique using alkoxy-silyl compounds clusters microplastic particles of any type, size, or density into larger aggregates that float to the water surface and can be removed with standard sand traps, offering a wastewater treatment approach that works independently of particle characteristics. This technology addresses a critical gap, as conventional wastewater treatment plants fail to capture the smallest microplastic particles that pass through into waterways.

Study Type Environmental

The substance class of inert organic-chemical stressors (IOCS) describes organic-chemical (macro-) molecules, which demonstrate a high level of persistence upon entry in the ecosystem, and whose degradation is limited. These synthetically produced organic-chemical macromolecules, which are often derived from the polymerization of different monomers, are, in the form of plastics, indispensable in the everyday world. They enter the environmental compartments and cause great damage due to primary (industry, cosmetic, washing of textile), and secondary (degradation) entry. If these particles get into aquatic systems, this has fatal consequences for the ecosystem such as the death of marine animals, or bioaccumulation. Wastewater treatment plants are reaching their limits and require innovative ideas for the sustainable removal of microplastic. This article examines a new approach to the removal of polymers from aquatic systems (lab scale) by using sol–gel induced agglomeration reactions to form larger particle agglomerates. These enlarged agglomerates can be separated much more easily from the wastewater, since they float on the water surface. Separation systems, e.g. sand trap can easily be used. A further advantage is that the agglomeration can be carried out completely independently of the type, size, and amount of the trace substance concentration as well as of the external influences (pH value, temperature, pressure). Thus, this new type of particle separation can not only be used in sewage treatment plants, but can also be transferred to decentralized systems (e.g. implementation in industrial processes).

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