We can't find the internet
Attempting to reconnect
Something went wrong!
Hang in there while we get back on track
Sorption of 3,6-dibromocarbazole and 1,3,6,8-tetrabromocarbazole by microplastics
Summary
Two brominated carbazole pollutants were found to readily adsorb onto polypropylene microplastics in seawater, with smaller plastic particles absorbing more chemical per unit mass. This demonstrates that microplastics can concentrate brominated organic pollutants from seawater and potentially deliver them to marine organisms.
Microplastics and organic pollutants are typical contaminants in the marine environment. However, little is known about their interactions. In this study, the sorption of 3,6-Dibromocarbazole(3,6-BCZ) and 1,3,6,8-Tetrabromocarbazole (1,3,6,8-BCZ) by Polypropylene microplastic in simulated seawater was studied. Factors, including particle size, salinity and concentration, were investigated, and the experimental results were simulated using a mathematical model. Results showed that the pseudo-second-order kinetic model was more suitable to describe the sorption of polyhalogenated carbazole by microplastics, with equilibrium sorption times of 6 h and 8 h for 3,6-BCZ and 1,3,6,8-BCZ, respectively. Sorption capacity increased with decreasing particle size and the adsorption capacity increased initially and then decreased with increasing salinity, with a maximum sorption occurring at salinity of 14%. Moreover, the sorption amount increased with the increasing concentration of polyhalogenated carbazole. The sorption isotherms were confirmed as the extended Langmuir model and the extended Freundlich model, both of which were S-type.
Sign in to start a discussion.
More Papers Like This
Sorption of polyhalogenated carbazoles (PHCs) to microplastics
Researchers investigated the sorption of five polyhalogenated carbazoles onto polyethylene, polypropylene, and polyvinyl chloride microplastics, finding that sorption capacity varied with plastic type and carbazole structure, indicating that microplastics can act as vectors for these emerging halogenated organic contaminants.
Sorption of representative organic contaminants on microplastics: Effects of chemical physicochemical properties, particle size, and biofilm presence
This study examined how organic pollutants like flame retardants and industrial chemicals attach to microplastics in saltwater conditions. Smaller microplastic particles absorbed more contaminants per unit weight, and natural biofilms growing on the plastic surfaces changed how much pollution they could carry. The findings help explain how microplastics act as carriers of toxic chemicals through the environment and potentially into the food chain.
Adsorption and Desorption Behaviour of Polychlorinated Biphenyls onto Microplastics’ Surfaces in Water/Sediment Systems
Researchers evaluated the adsorption and desorption behavior of polychlorinated biphenyls (PCBs) onto polystyrene, polyethylene, and polyethylene terephthalate microplastics of varying sizes in marine water/sediment systems. Results showed that polymer type and particle size influenced PCB binding capacity, with microplastics acting as potential vectors for transferring persistent organic pollutants to marine biota through the food chain.
Enrichment of Persistent Organic Pollutants in Microplastics from Coastal Waters
Researchers quantified how microplastics concentrate persistent organic pollutants compared to suspended particulate matter in coastal seawater. They found that the concentrating effect of microplastics on these pollutants was one to two orders of magnitude greater than that of natural suspended particles. The study provides precise measurements of enrichment factors, suggesting that microplastics may serve as significant carriers of toxic organic chemicals in marine environments.
Sorption and dissipation of current-use pesticides and personal-care products on high-density polyethylene microplastics in seawater
Researchers characterized how three pesticides and three personal care products sorb onto high-density polyethylene microplastics in seawater. They found that more hydrophobic compounds accumulated more readily on the plastic, and that significant desorption (over 30%) occurred within 24 hours, especially at higher contaminant concentrations. The study confirms that microplastics can act as both carriers and releasers of chemical pollutants in marine environments.