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A machine learning algorithm for high throughput identification of FTIR spectra: Application on microplastics collected in the Mediterranean Sea
Summary
Researchers developed a machine learning method to automatically identify the chemical composition of microplastics from FTIR spectroscopy data collected during the Tara Mediterranean expedition. The algorithm performed well for common polymers like polyethylene and was applied to classify over 4,000 unidentified microplastic spectra. The study demonstrates that automated identification tools can significantly speed up large-scale microplastic pollution surveys while maintaining acceptable accuracy.
The development of methods to automatically determine the chemical nature of microplastics by FTIR-ATR spectra is an important challenge. A machine learning method, named k-nearest neighbors classification, has been applied on spectra of microplastics collected during Tara Expedition in the Mediterranean Sea (2014). To realize these tests, a learning database composed of 969 microplastic spectra has been created. Results show that the machine learning process is very efficient to identify spectra of classical polymers such as poly(ethylene), but also that the learning database must be enhanced with less common microplastic spectra. Finally, this method has been applied on more than 4000 spectra of unidentified microplastics. The verification protocol showed less than 10% difference in the results between the proposed automated method and a human expertise, 75% of which can be very easily corrected.