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Synthesis, Thermal Properties and Decomposition Mechanism of Poly(Ethylene Vanillate) Polyester
Polymers2019
36 citations
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Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count.
Score: 35
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0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Researchers synthesized and characterized poly(ethylene vanillate), a bio-based polyester that could serve as a greener alternative to PET plastic. Developing bio-based plastics with good performance characteristics is important for reducing dependence on petroleum plastics that persist as microplastics in the environment.
Plastics are perceived as modern and versatile materials, but their use is linked to numerous environmental issues as their production is based on finite raw materials (petroleum or natural gas). Additionally, their low biodegradability results in the accumulation of microplastics. As a result, there is extensive interest in the production of new, environmentally friendly, bio-based and biodegradable polymers. In this context, poly(ethylene vanillate) (PEV) has a great potential as a potentially bio-based alternative to poly(ethylene terephthalate); however, it has not yet been extensively studied. In the present work, the preparation of PEV is reported. The enthalpy and the entropy of fusion of the pure crystalline PEV have been estimated for the first time. Additionally, the equilibrium melting temperature has also been calculated. Furthermore, the isothermal and non-isothermal crystallization behavior are reported in detail, and new insights on the thermal stability and degradation mechanism of PEV are given.