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Comprehensive Multi-Analytical Investigations on the Vietnamese lacquered Wall-Panel “The Return of the Hunters” by Jean Dunand
Summary
Researchers used multiple spectroscopic techniques to analyze the lacquer layers in a 1935 artwork by Jean Dunand, identifying natural Asian lacquer, oils, and mineral pigments. While unrelated to microplastics, advances in micro-ATR-FTIR spectroscopic mapping have direct applications in identifying the chemical composition of microplastic particles.
This work presents a comprehensive, multi-analytical scientific approach for determining the type of lacquer and artistic materials used by Jean Dunand on his work "The Return of the Hunters" (1935). For this purpose, thermally assisted hydrolysis and methylation - gas chromatography/mass spectrometry (THM-GC/MS), optical microscopy (OM) in visible (Vis) and ultraviolet light (UV), and scanning electron microscopy - energy-dispersive X-ray spectroscopy (SEM-EDX) were selected. Furthermore, a novel application of micro attenuated total reflection Fourier transform infrared (µATR-FTIR) spectroscopic mapping by univariate and multivariate analysis was applied for studying the complex lacquer paint stratigraphy. The results show that Vietnamese lacquer was used as a binder, mixed together with linseed oil and pine resins as additives in combination with inorganic pigments, and that shellac was included on the top of the paint; they document an important step in the story of the transfer of Vietnamese lacquer painting techniques to Europe.
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