Sedimentation of nanoplastics from water with Ca/Al dual flocculants: Characterization, interface reaction, effects of pH and ion ratios

Nanoplastics (NPs), which are broken down from large pieces of plastics and caused water environment pollution, are becoming an emerging environmental problem due to their stable structure, high mobility, and easy interactions with ambient organic compounds. Separation of NPs by flocculation may be an effective approach for remediation of NPs contaminated-water. Aluminum ion has been used as a highly efficient flocculant in sewage treatment, and calcium ion also shows excellent sedimentation performance for impurities under high pH conditions. In this study, composite metal calcium-aluminum (Ca/Al) ions were used as flocculants, achieving a settling efficiency of NPs almost as high as 80%. The effects of pH and Ca/Al flocculant ratios on the zeta potentials, solution stability, as well as sedimentation efficiency of NPs were investigated. Results showed that the crystal formation of Ca/Al flocs increased with pH. The contact and adsorption mechanism of NPs by Ca/Al flocs were confirmed by X-ray diffraction, scanning electron microscope, Fourier Transform Infrared Spectrometer, and X-ray photoelectron spectroscopy. The capture of NPs by Ca/Al flocculants could provide a new insight for the treatment of NPs from aqueous environment.