Nanofunctionalized Magnetic Carbon Composite for Treatment of Technogenically Contaminated Waters

Among the main man-made water pollutants that pose a danger to the environment are oil products, heavy metals, and radionuclides, as well as micro- and nanoplastics. To purify such waters, it is necessary to use advanced methods, with sorption being one of them. The aim of this work is to develop a nano-functionalized composite, comprising magnetically responsive, thermally expanded graphite (TEG) and the natural clay bentonite, and to assess its ability to purify man-made contaminated waters. Throughout the course of the research, the methods of scanning electron microscopy, optical microscopy, dynamic light scattering, radiometry, and atomic absorption spectrophotometry were used. The use of the TEG–bentonite composite for the purification of the model water, simulating radioactively contaminated nuclear power plant (NPP) effluent, reduced the content of organic substances by 10–15 times, and the degree of extraction of cesium, strontium, cobalt, and manganese was between 81.4% and 98.8%. The use of the TEG–bentonite composite for the purification of real radioactively contaminated water obtained from the object “Shelter” (“Ukryttya” in Ukrainian), in the Chernobyl Exclusion Zone, Ukraine, with high activity, containing organic substances, including micro- and nanoplastics, reduced the radioactivity by three orders of magnitude. The use of cesium-selective sorbents for additional purification of the filtrate allowed for further decontamination of radioactively contaminated water with an efficiency of 99.99%.