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An Overview of the Sorption Studies of Contaminants on Poly(Ethylene Terephthalate) Microplastics in the Marine Environment
Summary
This review examines how polyethylene terephthalate (PET) microplastics adsorb and release both organic and metallic contaminants in the marine environment. Researchers analyzed the sorption mechanisms and kinetic models used to study how pollutants bind to PET particles. The study underscores the growing concern that PET microplastics, one of the most common plastics found in ocean pollution, may serve as carriers for toxic chemicals in marine ecosystems.
Marine pollution is one of the biggest environmental problems, mainly due to single-use or disposable plastic waste fragmenting into microplastics (MPs) and nanoplastics (NPs) and entering oceans from the coasts together with human-made MPs. A rapidly growing worry concerning environmental and human safety has stimulated research interest in the potential risks induced by the chemicals associated with MPs/NPs. In this framework, the present review analyzes the recent advances in adsorption and desorption studies of different contaminants species, both organic and metallic, on MPs made of Poly(Ethylene terephthalate). The choice of PET is motivated by its great diffusion among plastic items and, unfortunately, also in marine plastic pollution. Due to the ubiquitous presence of PET MPS/NPs, the interest in its role as a vector of contaminants has abruptly increased in the last three years, as demonstrated by the very high number of recent papers on sorption studies in different environments. The present review relies on a chemical engineering approach aimed at providing a deeper overview of both the sorption mechanisms of organic and metal contaminants to PET MPs/NPs and the most used adsorption kinetic models to predict the mass transfer process from the liquid phase to the solid adsorbent.