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Synergistic effects of CO2 on complete thermal degradation of plastic waste mixture through a catalytic pyrolysis platform: A case study of disposable diaper
Summary
Researchers developed a catalytic pyrolysis platform using CO2 to completely decompose heterogeneous plastic waste mixtures, demonstrating complete thermal degradation of disposable diaper components into syngas without releasing toxic residues or microplastics.
Consumption of diverse plastics has posed an environmental threat because their disposal practices, landfilling and incineration, release toxic chemicals and microplastics into all environmental media. Indeed, heterogeneous matrix of plastic wastes makes them hard to be disposed. As such, this study aimed to introduce an environmentally benign/reliable disposal platform for complete decomposition of plastic wastes. Pyrolysis process was adapted to convert plastics into syngas, and a disposable diaper (DD) was used as model plastic waste, because it is composed of a variety of polymeric materials. Pyrolysis of DD resulted in the formation of gaseous products and pyrogenic oils, composed of (oxygenated) hydrocarbons. Nonetheless, reactivity of CO as an oxidant in pyrolysis of DD was negligible. To impart the strong/desired reactivity of CO, Ni-based catalyst was adopted. Ni catalyst enhanced H and CO formations 4 and 15 times more than pyrolysis without catalyst at 700 °C under CO. The value-added syngas production was originated from the reduction of polymeric waste, and its derivatives including aromatic compounds. Thus, CO offered a strategic means to produce value-added chemicals and reduce aromaticity of pyrogenic products. The observations could offer an innovative way to control the fate of toxic chemicals derived from plastic pyrolysis.
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