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Influence of CNT loading and environmental stressors on leaching of polymer-associated chemicals from epoxy and polycarbonate nanocomposites
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Researchers found that carbon nanotube loading and environmental stressors (temperature, UV light, pH) influence the leaching of polymer-associated chemicals from epoxy and polycarbonate nanocomposites, raising concerns about toxic compound release into the environment.
Environmental context Carbon nanotubes are added to polymers such as polycarbonate and epoxy to form nanocomposites with enhanced material properties. Environmental factors including temperature, UV light exposure and pH have the potential to degrade these composites and increase the release of toxic polymer-associated chemicals. This study investigates how carbon nanotube loading decreases the release of known endocrine-disrupting compounds, bisphenol A and 4-tert-butylphenol, from polymer nanocomposites under simulated weathering environments. Abstract Nanoparticles such as carbon nanotubes are increasingly added to polymer matrices to improve tensile strength and electrical and thermal conductivity, and to reduce gas permeability. During use and after disposal, these plastic nanocomposites (PNCs) are degraded into microplastics by physical and chemical processes including mechanical abrasion, UV light exposure, hydrolysis and oxidation. Such polymers have the potential to enter aquatic environments and release potentially hazardous polymer-associated chemicals and transformation products. This work identifies and quantifies polymer-associated chemicals leached from polymers and nanocomposites during simulated environmental exposure. Epoxy and polycarbonate PNCs containing single-walled carbon nanotube (SWCNT) loadings ranging from 0 to 1 wt-% were exposed to water for 5 days, and the release of the chemicals bisphenol A (BPA) and 4-tert-butylphenol (TBP) was measured. The role of UV exposure, pH, temperature and natural organic matter in regulating chemical release was also investigated. Temperature, pH and UV light were found to be the most significant factors influencing release of TBP and BPA from PNCs. Additionally, increasing carbon nanotube loading in both polycarbonate and epoxy composites was found to decrease the release of these phenolic chemicals. A 0.3 % higher SWCNT loading decreased the release of BPA 45 ± 18 %, and a 1 % SWCNT loading decreased chemical release from epoxy by 48 ± 26 % for BPA and 58 ± 8 % for TBP. This information provides important data that can be used to help assess the risks posed by SWCNT polymer nanocomposites in aqueous environments, particularly as they age and are transformed.
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Data from: Influence of CNT loading and environmental stressors on leaching of polymer associated chemicals from epoxy and polycarbonate nanocomposites
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Researchers examined how carbon nanotube (CNT) loading levels and environmental stressors influence the leaching of polymer-associated chemicals from epoxy and polycarbonate nanocomposites. The study found that physical and chemical degradation processes can cause these plastic nanocomposites to release potentially hazardous chemical additives into aquatic environments.
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Researchers studied the degradation of carbon nanotube-reinforced epoxy composites during accelerated weathering, finding that UV exposure causes fragmentation and release of both microplastics and embedded nanoparticles into the environment.
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