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Photoformation of environmentally persistent free radicals on particulate organic matter in aqueous solution: Role of anthracene and formation mechanism
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Researchers found that anthracene contamination in water generates environmentally persistent free radicals on particulate organic matter under light exposure, with these radicals persisting for up to 61 hours and subsequently driving indirect photodegradation of other pollutants like bisphenol A through reactive oxygen species production.
Environmentally persistent free radicals (EPFRs) generated under irradiation have been widely detected in soil particles, atmospheric particles and microplastic particles, but the formation of EPFRs in water is not well understood. This study investigated the formation of EPFRs on particulate organic matter (POM) in water contaminated by anthracene (Ant) under irradiation. The photoformation and decay progress of EPFRs was represented with the help of electron paramagnetic resonance (EPR) technique on both actual POM and Fe(III)-montmorillonite simulated samples. EPR signals at the range of 10 to 10 spin/g were detected and the half-life time of EPFRs stored in water was at around 16.62 h and 60.80 h, much shorter than those in the air. The g factors were all larger than 2.0040, which indicated the generation of oxygen centered EPFRs. The primary intermediates were identified by gas chromatography-mass spectrometer (GC-MS) and a possible EPFR formation pathway during Ant degradation was proposed. The interaction between Ant and POM, and the hydroxylation and carbonylation of the intermediates made contributions to the generation of EPFRs. Meanwhile, the indirect photodegradation of bisphenol A (BPA) has been demonstrated by analyzing the reactive oxygen species (ROS) and photogenerated electrons in the solution with POM containing EPFRs. It is found that hydroxyl radicals (•OH) and singlet oxygen (O) were induced and might promote the photodegration. Overall, our present study provided useful information to understand the photoformation of EPFRs on POM and their fate in aqueous environments.
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Researchers found that microplastic properties — including polymer type, surface chemistry, and aging state — govern the rate and pathway of solar photodegradation of sorbed anthracene in aquatic environments, with sorption to microplastics altering contaminant photochemical fate compared to free solution.
Microplastic PropertiesGovern the Photodegradationof Sorbed Anthracene in Aquatic Environments
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Researchers investigated how microplastic properties govern the photodegradation of anthracene, a model hydrophobic organic contaminant, in aquatic environments, finding that polymer type, surface characteristics, and aging state significantly influenced degradation rates. The study highlights that microplastics can both facilitate and inhibit contaminant photodegradation depending on their physicochemical properties.
Formation of environmentally persistent free radicals on microplastics under UV irradiations
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This study found that UV light from the sun creates long-lasting free radicals on the surface of microplastics, with stronger UV producing more radicals faster. These environmentally persistent free radicals are chemically reactive and can damage cells and DNA. The finding is important because it means sunlight-weathered microplastics in the environment may be more harmful than fresh plastics, carrying these damaging free radicals into the body when ingested or inhaled.
Elucidating the role of overlooked environmentally persistent free radicals and reactive chlorine species on photoaged chlorine-containing microplastics: New insights into formation mechanisms and health risks
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Researchers investigated the formation of environmentally persistent free radicals and reactive chlorine species on photoaged chlorine-containing microplastics like PVC and PVDC. The study revealed previously overlooked chemical transformations during microplastic aging that may pose additional health risks beyond the physical presence of the plastic particles themselves.
Formation of Environmentally Persistent Free Radicals on Microplastics under Light Irradiation
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Four types of virgin microplastics were aged under simulated solar irradiation and analyzed by electron paramagnetic resonance spectroscopy, finding that polystyrene and phenol-formaldehyde resin produced environmentally persistent free radicals (EPFRs) that decayed slowly, while polyethylene and PVC did not. The study identifies photoaged plastic surfaces as a previously unrecognized source of EPFRs—emerging contaminants with known health risks.
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