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Synthesis, Characterization and Adsorption of Bisphenol A Using Novel Hybrid Materiel Produced from PANI Matrix Reinforced by Kieselguhr

2021
Dalila Ouis, Abdelkader El Kebir, Imane Moulefera, Lilia Sabantina, Abdelghani Benyoucef

Summary

This study developed a novel composite adsorbent made from polyaniline and kieselguhr (diatomaceous earth) for removing bisphenol A from water. The hybrid material was characterized and demonstrated effective BPA adsorption capacity from aqueous solutions.

Abstract This study investigated the preparation of new adsorbent based PANI and Kieselguhr (KG). The produced materials were characterized by XRD, XPS, TEM, FTIR, TGA and BET. Thereby, hybrid material PANI@KG highest SBET values (about 47.82 m2.g−1). The adsorption capacity of the PANI, KG and PANI@KG were tested on BPA ions from aqueous solutions at ambient temperature and pH 6.0, the maximum capacity of adsorption was observed to be 63.68 mg.g−1 which is obtained from Langmuir adsorption isotherm by hybrid adsorbent PANI@KG. Besides, the pseudo-2nd order kinetics was more consistent with the obtained experimental data. Furthermore, the hybrid material possessed highest adsorption capacity after six cycles of adsorption-desorption process. Moreover above 80% of removal percentage was obtained even after three recycles. Hence we expect that this organic-inorganic adsorbent can be selected as a potential candidate for water treatment.

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