Ultra-efficient catalytic degradation of malachite green dye wastewater by KMnO₄-modified biochar (Mn/SRBC)

In this work, KMnO₄-modified biochar was prepared from spirulina residue as the research object. Herein, we report the synthesis, characterization, and catalytic degradation performance of KMnO₄-modified biochar, given that heterogeneous catalytic oxidation is an effective way to treat dye wastewater rapidly. The Mn/SRBC catalyst prepared by KMnO₄ modification was characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffractometry, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, nitrogen adsorption-desorption and laser Raman spectroscopy. In addition, we compared the results with that of the unmodified SRBC. The results showed that the Mn/SRBC catalyst prepared by KMnO₄ modification had a rich pore structure, which provided sufficient contact area for the catalytic reaction. In the presence of H₂O₂, the catalyst could be used to catalyze the oxidative degradation of malachite green in aqueous solution with ultra-high efficiency. In the experiment, the initial pH values of the reaction system had a significant influence on the reaction rate. The removal effect of biochar on the malachite green was poor in an alkaline environment. Within a specific range, the removal rate of malachite green was proportional to the concentration of H₂O₂ in the reaction system. The degradation rate of malachite green dye at 8000 mg L^-1 was about 99% in the presence of the catalyst over 5 mmol L^-1 hydrogen peroxide for 30 min. These results show the potential application of algae residue biochar and carbon-based composite catalysts for degrading and removing dye wastewater.