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Living in a transient world: ICP-MS reinvented via time-resolved analysis for monitoring single events

Chemical Science 2022 79 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count. Score: 45 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Martín Resano, Maite Aramendía, E. García-Ruiz, Antonio Bazo, Eduardo Bolea‐Fernandez, Frank Vanhaecke

Summary

This review describes how time-resolved ICP-MS analysis has transformed the technique from bulk elemental analysis into a tool for characterizing individual nanoparticles and single cells, enabling detection and characterization of nanoplastics and other nano-objects in complex samples.

After 40 years of development, inductively coupled plasma-mass spectrometry (ICP-MS) can hardly be considered as a novel technique anymore. ICP-MS has become the reference when it comes to multi-element bulk analysis at (ultra)trace levels, as well as to isotope ratio determination for metal(loid)s. However, over the last decade, this technique has managed to uncover an entirely new application field, providing information in a variety of contexts related to the individual analysis of single entities (e.g., nanoparticles, cells, or micro/nanoplastics), thus addressing new societal challenges. And this profound expansion of its application range becomes even more remarkable when considering that it has been made possible in an a priori simple way: by providing faster data acquisition and developing the corresponding theoretical substrate to relate the time-resolved signals thus obtained with the elemental composition of the target entities. This review presents the underlying concepts behind single event-ICP-MS, which are needed to fully understand its potential, highlighting key areas of application (e.g., single particle-ICP-MS or single cell-ICP-MS) as well as of future development (e.g., micro/nanoplastics).

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