We can't find the internet
Attempting to reconnect
Something went wrong!
Hang in there while we get back on track
Investigation of the adsorption behavior of Pb(II) onto natural-aged microplastics as affected by salt ions
AI summary Read the abstract
Researchers found that naturally aged microplastics adsorb significantly more lead than virgin microplastics, and that calcium chloride in solution strongly inhibits lead adsorption, indicating that environmental weathering and water chemistry alter contaminant transport.
In this study, the adsorption behavior of Pb(II) on natural-aged and virgin microplastics in different electrolyte solutions was investigated. The results demonstrated that natural-aged microplastics exhibited higher adsorption capacity for Pb(II) compared to virgin ones, and the addition of CaCl strongly inhibited the adsorption amount of Pb(II). The adsorption kinetics of Pb(II) adsorption were better fitted by the pseudo-second order model and Elovich equation, and were slowed down greatly at higher ionic strength. The rate-limiting steps of adsorption process were dominated by intra-particle diffusion. The adsorption isotherm of Pb(II) onto microplastics affected by salt ions can be well described by Freundlich model, the greater adsorption efficiency of natural-aged microplastics proved that adsorption process was multilayer and heterogeneous. In addition, pH significantly influenced the adsorption of Pb(II) due to the changes electrostatic interactions. The effect of fulvic acid in the electrolyte solutions was also revealed and attributed to the complexation with Na and Ca. Furthermore, the higher pH and ionic strength in different environmental water dramatically decreased adsorption capacity onto microplastics. Finally, it's confirmed that the adsorption mechanisms affected by salt ions mainly involve electrostatic interaction, surface complexation, and ionic exchange. These findings indicate that salt ions exert an important influence on the adsorption of heavy metals for MPs, which should be further concerned.
More Papers Like This
Adsorption behaviour of accelerated UV aged PET and PP microplastics towards Pb(II) under varying pH, temperature, and salinity conditions
AI summary Read the abstract
UV aging causes PET and PP microplastics to adsorb significantly more lead (Pb) from water, with the extent varying by pH, temperature, and salinity. This means weathered microplastics in the environment may carry greater toxic metal loads than virgin plastic, amplifying their hazard to ecosystems and human health.
Insights Into the Adsorption Behavior of Polyethylene Microplastics Towards Lead(II) Ions
AI summary Read the abstract
Researchers investigated the adsorption behavior of lead(II) ions onto polyethylene microplastics in freshwater environments by systematically varying initial Pb(II) concentration, pH, and residence time, using scanning electron microscopy and other characterization methods to elucidate the interaction dynamics and sorption mechanisms between this common metal contaminant and microplastic surfaces.
Study on the Adsorption Behavior and Mechanism of Heavy Metals in Aquatic Environment before and after the Aging of Typical Microplastics
AI summary Read the abstract
Researchers investigated the adsorption behavior and mechanisms of heavy metals by typical microplastics before and after environmental aging, finding that aging significantly alters microplastics' surface properties and capacity to bind metals such as cadmium and lead in aquatic systems.
Mechanism analysis of heavy metal lead captured by natural-aged microplastics
AI summary Read the abstract
The mechanism by which naturally aged microplastics capture lead (Pb(II)) from aqueous solution was investigated by comparing pristine and aged particles. Aged microplastics adsorbed more Pb(II) than pristine ones, with weathering-induced surface oxidation and increased oxygen-containing functional groups driving the enhanced metal capture capacity.
Comparative analysis of kinetics and mechanisms for Pb(II) sorption onto three kinds of microplastics
AI summary Read the abstract
The sorption kinetics and mechanisms of lead (Pb(II)) onto three types of microplastics were compared to understand how plastic debris concentrates heavy metals in aquatic environments. The study found polymer-specific differences in sorption capacity and mechanism, with implications for how microplastics alter the distribution and bioavailability of lead in contaminated water.
Research digests by email
When a large batch of papers lands in the Atlas, we read through it and send a short write-up of what stood out.