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A Review on Biological Synthesis of the Biodegradable Polymers Polyhydroxyalkanoates and the Development of Multiple Applications
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This review covers the biological production of polyhydroxyalkanoates, a family of biodegradable bioplastics that bacteria naturally produce from waste carbon sources. Researchers found that these biopolymers have properties similar to conventional plastics like polypropylene but can fully biodegrade, making them a promising alternative to petroleum-based plastics. The study emphasizes that scaling up production and establishing proper end-of-life management are critical steps for PHAs to compete with conventional plastics and help reduce microplastic pollution.
Polyhydroxyalkanoates, or PHAs, belong to a class of biopolyesters where the biodegradable PHA polymer is accumulated by microorganisms as intracellular granules known as carbonosomes. Microorganisms can accumulate PHA using a wide variety of substrates under specific inorganic nutrient limiting conditions, with many of the carbon-containing substrates coming from waste or low-value sources. PHAs are universally thermoplastic, with PHB and PHB copolymers having similar characteristics to conventional fossil-based polymers such as polypropylene. PHA properties are dependent on the composition of its monomers, meaning PHAs can have a diverse range of properties and, thus, functionalities within this biopolyester family. This diversity in functionality results in a wide array of applications in sectors such as food-packaging and biomedical industries. In order for PHAs to compete with the conventional plastic industry in terms of applications and economics, the scale of PHA production needs to grow from its current low base. Similar to all new polymers, PHAs need continuous technological developments in their production and material science developments to grow their market opportunities. The setup of end-of-life management (biodegradability, recyclability) system infrastructure is also critical to ensure that PHA and other biobased biodegradable polymers can be marketed with maximum benefits to society. The biobased nature and the biodegradability of PHAs mean they can be a key polymer in the materials sector of the future. The worldwide scale of plastic waste pollution demands a reformation of the current polymer industry, or humankind will face the consequences of having plastic in every step of the food chain and beyond. This review will discuss the aforementioned points in more detail, hoping to provide information that sheds light on how PHAs can be polymers of the future.
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Polyhydroxyalkanoates as multifaceted biopolymers: an eco-friendly alternative to conventional plastics.
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Plastic pollution and the microplastics it creates are a growing health concern, but this review paper looks at a promising fix: plastics made by bacteria instead of fossil fuels, called PHAs, which naturally break down without leaving lasting waste. The researchers summarize existing studies on how to grow and produce these bacteria-made plastics more efficiently and affordably, since high costs are still the main reason they haven't replaced regular plastic on store shelves. While PHAs aren't widely available yet, this research maps out what's needed to make them a real, scalable alternative that could reduce our exposure to plastic waste in the environment
Current trends in the production of biodegradable bioplastics: The case of polyhydroxyalkanoates
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This review evaluates the state of polyhydroxyalkanoate (PHA) bioplastic production, comparing microbiological, enzymatic, and chemical manufacturing approaches for their potential to replace petroleum-based plastics. While PHAs are naturally biodegradable and mechanically versatile, cost and scalability remain major barriers to commercial adoption.
Bacterial Production of Hydroxyalkanoates (PHA)
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This review examines bacterial production of polyhydroxyalkanoates (PHA) as a biodegradable alternative to petroleum-based plastics, covering fermentation processes, scaling to industrial levels, and future trends, while noting that higher production costs currently prevent PHAs from competing commercially with conventional plastics.
Polyhydroxyalkanoates (PHAs) – Production, Properties, and Biodegradation
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This review covers polyhydroxyalkanoates (PHAs), a class of microbially produced biopolyesters, discussing raw material innovation, microbial producer strains, bioengineering approaches for improved yields, and end-of-life biodegradation options. PHAs are presented as a genuinely circular plastic alternative due to their renewable production, biodegradability, and compatibility with existing plastic applications including food packaging.
Biosynthesis of Polyhydroxyalkanoates (PHAs) by the Valorization of Biomass and Synthetic Waste
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This paper explores the production of polyhydroxyalkanoates (PHAs), biodegradable microbial polymers, from biomass and waste feedstocks as a sustainable alternative to conventional synthetic plastics. PHAs can be naturally synthesized by bacteria, offering a pathway to biodegradable plastics that do not persist as microplastic pollution.
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