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Chemical Leaching from Tire Wear Particles with Various Treadwear Ratings
Summary
Researchers investigated how tire treadwear ratings affect chemical leaching from tire wear particles, finding that benzothiazole compounds leached at different rates depending on tire type, with an additional derivative (2-mercaptobenzothiazole) detected by high-resolution mass spectrometry. The findings suggest that using benzothiazole alone as a quantification marker for tire wear particles can lead to inaccurate estimates of environmental contamination.
Physical friction between a tire and the road surface generates tire wear particles (TWPs), which are a source of microplastics and particulate matter. This study investigated the trends of chemical leaching from TWPs depending on the treadwear rating of the tire. A road simulator was used to produce TWPs from tires with various treadwear ratings. Liquid chromatography-tandem mass spectrometry was used to analyze the chemical leaching from TWPs, with a particular focus on benzothiazole and its derivative 2-hydroxy benzothiazole. However, chemical mapping via high-resolution tandem mass spectrometry detected another derivative: 2-mercaptobenzothiazole. The benzothiazole groups were observed to have different leaching tendencies, implying that using benzothiazole as a marker compound may lead to incorrect TWP quantitation. The results of this research also suggest that the ecotoxicological influence of TWPs can vary with the treadwear rating of a tire.