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Interactions of pristine and aged nanoplastics with heavy metals: Enhanced adsorption and transport in saturated porous media
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Researchers found that UV-aged nanoplastics had greater capacity to adsorb and transport lead and cadmium through porous media compared to pristine nanoplastics, due to increased oxygen-containing surface groups that enhance heavy metal binding.
Interactions of nanoplastics (NPs) with other contaminants are attracting attention, and it is essential to investigate the interaction of aged plastics with heavy metals. We obtained aged nanopolystyrene by UV radiation and investigated the effects of aged NPs on the adsorption and cotransport of Pb-(II) and Cd-(II). The results showed that the UV-aged NPs led to the enhanced adsorption capacity of heavy metals due to the increase in oxygen-containing functional groups, and the promotion of transport by the aged NPs to heavy metals was stronger than that of the pristine NPs. Furthermore, the heavy metals retained in the columns could be freed by the NPs, and the aged NPs were more capable of freed of heavy metals as carriers. In conclusion, the radiation of NPs is correlated with their ability to promote heavy metal transport, and the oxygen content on the surface of NPs plays an essential role in this process to promote the transport of heavy metals in porous media. The ADR equation and DLVO theory simulates the transport behaviour of NPs well. This study is expected to provide a new perspective for assessing the potential risk of aged NPs in soil-groundwater systems.
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Researchers found that microplastics aged by UV sunlight are better at absorbing and carrying lead (a toxic heavy metal) through soil and water than fresh microplastics. The aging process changes the microplastic surface in ways that make it grab onto more lead, potentially spreading this toxic metal further through the environment. This is relevant to human health because aged microplastics in the real world may be transporting more heavy metals into water supplies and food-growing soil than previously thought.
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Researchers found that cadmium ions accelerate the photoaging of functionalized nanoplastics under UV irradiation, altering the surface chemistry and fragmentation behavior of the particles and increasing the production of potentially toxic nanoplastic breakdown products.
The effect of UV exposure on conventional and degradable microplastics adsorption for Pb (II) in sediment
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Researchers studied how UV aging affects the ability of conventional polyethylene and degradable polylactic acid microplastics to adsorb lead ions from aquatic sediment. They found that UV aging increased the surface area and oxygen content of both plastic types, enhancing their capacity to adsorb heavy metals. The study suggests that weathered microplastics in the environment may be more effective carriers of heavy metal contamination than pristine particles.
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Researchers aged polystyrene microplastics using UV irradiation under three conditions (air, pure water, seawater) and found that aging changed surface chemistry and increased the microplastics' capacity to adsorb heavy metals, with seawater aging producing the most pronounced surface oxidation.
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When a large batch of papers lands in the Atlas, we read through it and send a short write-up of what stood out.