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Microplastic removal from urban stormwater: Current treatments and research gaps
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Researchers investigated the phototransformation of polystyrene microplastics under simulated solar radiation, finding surface oxidation and formation of carbonyl groups after UV exposure. Photo-aged particles showed increased release of dissolved organic carbon and greater toxicity to marine copepods.
Stormwater is a major contributor to microplastic (MP) pollution in the aquatic environment. Although MPs are associated with many toxicological effects, their levels in stormwater are not regulated. This review compared the effectiveness of different MP removal technologies from stormwater runoff and examined the performance of typical stormwater treatment systems for MP removal to assess possible MP pollution control via stormwater management. Bioretention and filtration systems performed similarly with 84-96% MP removal efficiencies. Despite the limited number of studies that focused on wetlands and retention ponds, preliminary data suggested potential for MP removal with efficiencies of 28-55% and 85-99%, respectively. Despite the higher efficiency of bioretention and filtration systems, their removal efficiency of fibrous MPs was not optimal. Furthermore, wetlands were less effective in removing MPs than retention ponds, although the limited data might lead to an inaccurate representation of typical performances. Therefore, more research is required to arrive at definitive conclusions and to investigate alternative treatment options, such as ballasted sand flocculation, flotation, and biological degradation, and evaluate the effectiveness of bioretention and filtration for MPs <100 μm.
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Investigation of Surface Alteration of Microplastics by Using UV Irradiation
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UV radiation causes polystyrene and other plastic microparticles to undergo photooxidative degradation, changing their surface chemistry and potentially making them more likely to adsorb or release chemical pollutants. Understanding these weathering processes is important for predicting the environmental behavior and toxicity of microplastics.
Medium- and long-chain chlorinated paraffins in air: A review of levels, physicochemical properties, and analytical considerations
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Researchers examined how sunlight-driven photo-aging of polystyrene microplastics alters their surface chemistry and toxicity to marine copepods. Photo-aged particles showed greater adsorption of hydrophobic pollutants and caused higher mortality in Tigriopus japonicus than pristine particles.
Molecular characteristics and plastic additives in dissolved organic matter derived from polystyrene microplastics: Effects of cumulative irradiation and microplastic concentrations
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This study investigated how ultraviolet light breaks down polystyrene microplastics and releases dissolved organic matter, including plastic additives, into the surrounding water. Greater UV exposure produced more complex chemical mixtures with higher levels of potentially toxic compounds. The findings are important because sunlight-driven breakdown of microplastics in the environment may release harmful chemicals into water sources that people use for drinking and recreation.
Progress on the photo aging mechanism of microplastics and related impact factors in water environment
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This review examined the photo-aging mechanisms of microplastics in aquatic environments, finding that solar UV radiation drives oxidation reactions that alter surface chemistry, fragment particles further, and enhance their capacity to adsorb and release co-occurring pollutants.
Effects of photochlorination on the physicochemical transformation of polystyrene nanoplastics: Mechanism and environmental fate
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Researchers studied how sunlight combined with chlorine in water treatment changes the properties of polystyrene nanoplastics. They found that solar irradiation significantly accelerated the chemical breakdown of the nanoplastics, including surface oxidation and the release of organic compounds. The study reveals that nanoplastics leaving wastewater treatment plants undergo rapid transformation in the environment, which could alter both their fate and toxicity.
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When a large batch of papers lands in the Atlas, we read through it and send a short write-up of what stood out.