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Electrochemical and physicochemical degradability evaluation of printed flexible carbon electrodes in seawater

Journal of Electroanalytical Chemistry 2022 4 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count. Score: 30 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Fabiane Fantinelli Franco, Saoirse Dervin, Libu Manjakkal

Summary

Researchers developed a biodegradable, graphite-based electrode printed on a plant-derived plastic that can monitor water quality and dissolves quickly in seawater after use, offering an eco-friendly alternative to conventional sensor materials that leave behind non-degradable plastic and metal pollution.

The environmental impact of metals and non-degradable plastics in printed electrodes has highlighted the need of employing sustainable materials in environmental monitoring. In this work, we developed a new sustainable graphite-based paste (G-PE) printed on a bioderived and biodegradable polyhydroxybutyrate polyhydroxyvalerate substrate for tap water and seawater monitoring. We compared its performance against two standard screen-printed electrodes (SPEs) fabricated using commercial silver and carbon pastes (Ag-SPEs and C-SPEs) printed on a polyvinyl chloride substrate. The Ag-SPEs exhibited the lowest sheet resistance (RS = 0.053 Ω/sq), however they were also less reliable as silver oxidised and reacted with ions present in seawater. Meanwhile, the C-SPEs and G-PE presented similar RS (26.9 and 30.1 Ω/sq, respectively), were inert in different media and showed relatively stable response during cyclic bending studies (less than 2.3% relative resistance variation for the C-SPE). Physical and chemical degradation studies of the sustainable G-PE in seawater demonstrated relatively quick ultrasound induced dissolution (less than5 min) while the SPEs did not dissolve even after 30 min of sonication, highlighting the suitability of this new, eco-friendly G-PE for single use or short-term water quality monitoring applications.

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