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Recent Advances in Photocatalytic Removal of Microplastics: Mechanisms, Kinetic Degradation, and Reactor Design

Frontiers in Marine Science 2022 89 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count. Score: 60 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Wael Hamd Wael Hamd Wael Hamd Elie A. Daher, Elie A. Daher, Tajkia Syeed Tofa, Tajkia Syeed Tofa, Tajkia Syeed Tofa, Tajkia Syeed Tofa, Elie A. Daher, Tajkia Syeed Tofa, Joydeep Dutta, Joydeep Dutta, Joydeep Dutta, Joydeep Dutta, Joydeep Dutta, Wael Hamd Joydeep Dutta, Elie A. Daher, Joydeep Dutta, Joydeep Dutta, Wael Hamd Wael Hamd Joydeep Dutta, Joydeep Dutta, Wael Hamd Wael Hamd

Summary

This review examines how photocatalytic processes, which use light-activated materials to generate reactive molecules, can be used to break down microplastics in water. Researchers surveyed the mechanisms behind photocatalytic degradation of common plastics like polyethylene and polystyrene, as well as reactor designs that could make the technology practical. The study highlights photocatalysis as a promising approach for tackling microplastic pollution but notes that scaling up these systems remains a major challenge.

Polymers

Plastic products are used in almost all aspects of our daily life. Due to their low cost, portability, durability, and resistance to degradation, these products are affecting the health of the environment and biota on a global scale. Thus, the removal and mineralization of microplastics is an important challenge in the 21st century. Advanced oxidation processes (AOPs) have recently been identified as a viable treatment technique for tackling recalcitrant organic molecules and polymers. However, information on kinetic degradation mechanisms and photocatalytic reactor design is insufficient. This review discusses the fundamentals of photocatalysis and photo-Fenton processes in addition to the photocatalytic degradation mechanisms. We also introduce different characterization techniques of the major microplastic pollutants such as PE, PP, PVC, PS, PMMA, and PA66. In addition, a detailed overview of the major existing photocatalytic plants and the scaling-up methods of photoreactors are discussed.

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