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Sensitivity of the Transport of Plastic Nanoparticles to Typical Phosphates Associated with Ionic Strength and Solution pH
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This study investigated how phosphate ions in soil pore water influence the transport of plastic nanoparticles through porous media under varying pH and ionic strength conditions. Phosphate affected nanoparticle surface charge and aggregation behavior, altering how far particles traveled. The findings are relevant to understanding how plastic nanoparticles move through soils and groundwater systems.
The influence of phosphates on the transport of plastic particles in porous media is environmentally relevant due to their ubiquitous coexistence in the subsurface environment. This study investigated the transport of plastic nanoparticles (PNPs) via column experiments, paired with Derjaguin-Landau-Verwey-Overbeek calculations and numerical simulations. The trends of PNP transport vary with increasing concentrations of NaH2PO4 and Na2HPO4 due to the coupled effects of increased electrostatic repulsion, the competition for retention sites, and the compression of the double layer. Higher pH tends to increase PNP transport due to the enhanced deprotonation of surfaces. The release of retained PNPs under reduced IS and increased pH is limited because most of the PNPs were irreversibly captured in deep primary minima. The presence of physicochemical heterogeneities on solid surfaces can reduce PNP transport and increase the sensitivity of the transport to IS. Furthermore, variations in the hydrogen bonding when the two phosphates act as proton donors will result in different influences on PNP transport at the same IS. This study highlights the sensitivity of PNP transport to phosphates associated with the solution chemistries (e.g., IS and pH) and is helpful for better understanding the fate of PNPs and other colloidal contaminants in the subsurface environment.
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Scientists used laboratory experiments and molecular simulations to study how phosphate and calcium ions in soil water affect whether polystyrene nanoplastics move freely through the ground or get trapped in soil particles. They found that pH was a key factor: at lower pH levels, phosphate helped nanoplastics travel farther while calcium restricted movement, with both effects linked to how these ions change the surface charge of both the particles and the soil. Understanding nanoplastic mobility in soil is essential for predicting contamination of groundwater and crops.
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Researchers investigated the transport of nanoplastic particles through saturated porous media representative of groundwater aquifers, finding that particle surface charge and ionic strength of water significantly affected mobility. This study demonstrates that nanoplastics can travel substantial distances in subsurface environments, posing a risk to groundwater quality.
Effects of particle size and surface chemistry on plastic nanoparticle transport in saturated natural porous media.
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Researchers studied how the size and surface chemistry of plastic nanoparticles affect how they move through soil and are taken up by plants. They found that smaller particles and those with certain surface charges moved more readily through soil and were more likely to enter plant roots. The results indicate that nanoplastic contamination of agricultural soils could lead to plant uptake and potential transfer into the food chain.
Transport of polystyrene nanoplastics in natural soils: Effect of soil properties, ionic strength and cation type
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Researchers used column experiments across three soil types to show that polystyrene nanoplastic transport is governed by soil iron and aluminum oxide content and pH — with high-pH, low-oxide soils allowing up to 97% nanoplastic passage — and that calcium ions and higher ionic strength significantly increase retention, revealing that soil chemistry strongly controls nanoplastic mobility toward groundwater.
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Laboratory sand column experiments showed that polyethylene microplastic transport is inhibited by high ionic strength (as it reduces the repulsion between particles and sand grains) but enhanced by fulvic acid (which increases surface charge repulsion). The study provides mechanistic data for predicting how microplastics move through soils under different environmental chemical conditions.
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