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Nano/microplastics: Fragmentation, interaction with co-existing pollutants and their removal from wastewater using membrane processes
Summary
This review explores how nano- and microplastics fragment from larger plastic debris and interact with other pollutants like heavy metals and pharmaceuticals in water environments. Researchers examined how these tiny particles can adsorb hazardous substances onto their surfaces, potentially increasing health risks for humans and aquatic organisms. The study also evaluates membrane-based filtration technologies as promising methods for removing these combined contaminants from wastewater.
NANO: and microplastic (NP/MP) is one of the most challenging types of micropollutants, coming from either direct release or degradation of plastic items into ecosystems. NP/MP can adsorb hazardous pollutants (such as heavy metals and pharmaceutical compounds) and pathogens onto their surface that are consumed by humans, animals, and aquatic living organisms. This paper presents the interaction of NP/MP with other pollutants in the water environment and mechanisms involved to enable the ultimate fate of NP/MP as well as the effectiveness of metal-organic frame (MOF)-based membrane over conventional membrane processes for NP/MP removal. It is found that conventional membranes could remove MPs when their size is usually more than 1000 nm, but they are ineffective in removing NPs. These NPs have potentially greater health impacts due to their greater surface area. MOF-based membrane could effectively remove both NP and MP due to its large porous structure, high adsorption capacity, and low density. This paper also discusses some challenges associated with MOF-based membranes for NP/MP removal. Finally, we conclude a specific MOF-based ultrafiltration membrane (ED-MIL-101 (Cr)) that can potentially remove both negative and positive charged NP/MP from wastewater by electrostatic attraction and repulsion force with efficient water permeability.
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