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Plastic additives and microplastics as emerging contaminants: Mechanisms and analytical assessment

TrAC Trends in Analytical Chemistry 2022 194 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count.
João Pinto da Costa, Astrid Avellan, Catherine Mouneyrac, Armando C. Duarte, Teresa Rocha‐Santos

Summary

Researchers reviewed how chemical additives mixed into plastics during manufacturing — including stabilizers, flame retardants, and plasticizers — can leach out throughout a plastic's lifecycle and pose risks to ecosystems and human health, with microplastics acting as carriers that concentrate and transport these hazardous chemicals.

Plastic additives comprise a plethora of substances that serve numerous purposes in the plastic industry. These can be used to assist the molding of plastics and can contribute to providing optimal performance to the material when molded and used, or, simply, to reduce costs. However, these additives, and non-polymerized monomers, far more hazardous than their poly-counterparts, may be released throughout the entire life cycle of plastics, posing risks to the environment and, ultimately, human health. Hence, many studies have delved into the mechanistic uptake/release of these compounds. Herein, we briefly overview the current knowledge on the underlying processes affecting these mechanisms. We also outline the potential ecological consequences of these hazardous substances and explore some of the prevailing analytical methodologies used for their determination in both environment and laboratory studies. Furthermore, we highlight the key limitations of the currently available literature and present a prospective outlook for future research.

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