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Engineering chitosan into fully bio-sourced, water-soluble and enhanced antibacterial poly(aprotic/protic ionic liquid)s packaging membrane
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Researchers designed a water-soluble, antibacterial chitosan-based packaging film using fully bio-sourced materials, addressing growing concerns about microplastic pollution from conventional packaging. The resulting membrane showed enhanced antibacterial performance while remaining environmentally benign.
The design and facile preparation of water-soluble and eco-friendly polymer packaging membrane materials is a fascinating research topic, particularly in terms of the increasing concerns on potential microplastics pollution in ecosystem. In this study, taking advantages of the structural features of chitosan (CS) and betaine hydrochloride (BHC), fully bio-sourced and water-soluble poly(aprotic/protic ionic liquid)s (PAPILs) were successfully designed and prepared through the reaction of the amino groups in CS and carboxyl groups in BHC. The structure and thermo-properties of the PAPILs were elucidated by a series of characteristic methods. The rheological properties of the PAPILs aqueous solutions were also investigated. Moreover, water-soluble PAPILs membrane with a smooth surface morphology and a tensile strength of 62.9 MPa was successfully prepared. The PAPILs membrane also exhibited satisfactory biocompatibility, excellent antibacterial activities and high oxygen barrier property. Together with these outstanding material performance and functionality, as a "proof of concept", the potential use of the PAPILs membrane as water-soluble packaging material for laundry detergent capsule and pesticide was preliminarily demonstrated. These findings provide significant insights for the design of sustainable and functional packaging materials by using natural resources.
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When a large batch of papers lands in the Atlas, we read through it and send a short write-up of what stood out.