Laboratory simulated aging methods, mechanisms and characteristic changes of microplastics: A review

Microplastics (MPs) aging occurs in all environmental medias and affects the environmental behaviour and toxicity of MPs. Due to the extremely slow process of aging, laboratory simulated aging methods have had to be used to research the properties, behaviour, toxicity and effects of aged MPs. However, multiple laboratory aging methods with different mechanisms have led to divergent viewpoints on the characteristics, behavior and toxicity of aged MPs. Therefore, this paper reviewed the main laboratory MPs aging methods and mechanism, including those that involve UV, advanced oxidation processes (AOPs), sunlight or simulated sunlight, chemical treatment, heat, plasma radiation, etc. As a technology with a low time cost, AOPs have potential and are recommended. Physical, chemical, and coupled aging significantly alter MPs surface topography and functional groups, which affect MPs adsorption, migration and toxicity. However, the effects of aging on environmental behaviour and toxicity are highly uncertain. The carbonyl index (CI) and O/C ratio are generally applied to evaluate the MPs aging degree. This review highlights the need to provide adequate information on coupled simulated aging methods to allow better elucidation of the underlying mechanisms of aging and its effect on MPs environmental behaviour and toxicity.