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Characteristics and behaviors of microplastics undergoing photoaging and Advanced Oxidation Processes (AOPs) initiated aging

Water Research 2023 126 citations

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This review examines how microplastics change as they age in the environment through sunlight exposure and chemical processes. Aging alters the surface properties of microplastics, making them better at absorbing toxic chemicals and heavy metals from the surrounding environment. Since nearly all microplastics found in nature have undergone some degree of aging, understanding these changes is essential for accurately assessing how dangerous real-world microplastic pollution is to human health.

The fact that 94% of microplastics (MPs) ubiquitous in the environment are subject to natural weathering makes the aging study currently a research hotspot. This review summarized the physicochemical characteristics of MPs undergoing natural and artificial aging and evaluated current analytical methods used in aging studies. Besides, the differences in photoaging and aging induced by advanced oxidation processes (AOPs) were discussed, leading to a conclusion that AOPs composed of oxidant and ultraviolet (UV) irradiation can better facilitate the alteration of MPs compared to UV irradiation alone. In addition, the environmental behavior of aged MPs was outlined and their adsorption properties for organics and metals were highlighted as a result of combined effects of hydrophobic, π-π, diffusion, and hydrogen bond interaction. Furthermore, the mechanisms of photoaging and AOPs-initiated aging were analyzed, mainly the role of reactive oxygen species (ROS) and environmentally persistent free radicals (EPFRs). Finally, the applications of two-dimensional correlation spectroscopy (2D-COS) and three-dimensional fluorescence spectra using excitation emission matrix-parallel factor analysis (EEM-PARAFAC) were discussed for the aging process analysis. This overview plays an important role in explaining the aging characteristics of MPs and provides a theoretical foundation for further investigations into their toxicity and removal.

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