Influences of input concentration, media particle size, metal cation valence, and ionic concentration on the transport, long-term release, and particle breakage of polyvinyl chloride nanoplastics in saturated porous media

The environmental impact of nanoplastics has gradually attracted widespread attention; however, nanoplastics of polyvinyl chloride, one of the most commonly used plastics, have not yet been studied. In this study, we investigated the transport, long-term release behavior, and particle fracture of polyvinyl chloride nanoplastics (PVC NPs) in saturated quartz sand with different metal cations, ionic concentrations, input concentrations, and sand grain sizes by determining breakthrough, long-term release, and particle size distribution curves. The breakthrough curves and retention profiles were simulated by a mathematical model. The transport of PVC NPs increased with increased input concentration and sand grain size, which could be predicted by the Derjaguin-Landau-Verwey-Overbeek (DLVO) and colloid filtration theories. Increased ionic concentration and metal cation valence could restrain the transport of PVC NPs in saturated quartz sand owing to the decreased energy barrier between PVC NPs and sand grains. The total released amount of PVC NPs in the long-term release tests with different experimental conditions ranged from 3.91 to 21.95%. Increased sand grain size and decreased metal cation valence and ionic concentration resulted in an increased released amount of retained PVC NPs in saturated quartz sand, indicating increased release ability and mobility. The particle fracture results indicated that the PVC NPs were not broken down during long-term release under the experimental conditions of this research. This opens up a completely new and meaningful study of whether nanoplastics are broken down into smaller nanoplastics during their long-term release under various conditions.