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Aggregation Kinetics and Stability of Biodegradable Nanoplastics: Effects of Weathering and Proteins
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Researchers studied how weathering and proteins affect the aggregation and stability of biodegradable nanoplastics in water. Biodegradable plastics can still generate persistent nanoscale particles that behave differently depending on environmental conditions, complicating assumptions about their safety compared to conventional plastics.
Plastic pollution caused by conventional plastics has promoted the development and application of biodegradable plastics. However, biodegradable plastics do not degrade readily in water, instead, they can generate countless micro- and nanoplastics. Compared to microplastics, nanoplastics are more likely to cause negative impacts to the aquatic environment due to their smaller size. The impacts of biodegradable nanoplastics highly depend on their aggregation behavior and colloidal stability, which still remain unknown. Here, we studied the aggregation kinetics of polybutylene adipate co-terephthalate (PBAT) nanoplastics in both NaCl and CaCl2 solutions before and after artificial weathering. We further studied the effect of proteins on aggregation kinetics with both negatively charged bovine serum albumin (BSA) and positively charged lysozyme (LSZ). We found that divalent cations (Ca2+) destabilized PBAT nanoplastics more aggressively than monovalent cations (Na+); weathering stabilized PBAT nanoplastics profoundly, with no aggregation observed in NaCl nor in CaCl2; both BSA and LSZ promoted the aggregation of pristine PBAT nanoplastics, with LSZ showing more pronounced effect. These results suggest that biodegradable nanoplastics, especially weathered biodegradable nanoplastics, are highly stable in the aquatic environment.
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Aggregation kinetics and stability of biodegradable nanoplastics in aquatic environments: Effects of UV-weathering and proteins
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Researchers investigated the aggregation behavior of biodegradable nanoplastics (PBAT) in aquatic environments, finding that UV weathering and protein presence significantly alter their colloidal stability and aggregation kinetics, which influences their environmental fate and transport.
Weathering pathways differentially affect colloidal stability of nanoplastics
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This study showed that different environmental weathering pathways — UV exposure, mechanical abrasion, and chemical aging — differentially affect nanoplastic aggregation behavior, with implications for how their colloidal stability and environmental transport should be assessed in risk evaluations.
Aggregation kinetics of UV irradiated nanoplastics in aquatic environments
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Researchers compared the aggregation behavior of fresh versus UV-aged polystyrene nanoplastics under various aquatic conditions. They found that UV aging altered the surface chemistry of nanoplastics, making them more stable in water and less likely to aggregate, which means they could remain suspended and bioavailable for longer periods. The study suggests that weathered nanoplastics may behave very differently from fresh particles in the environment, complicating risk assessments.
Nanoplastics display strong stability in aqueous environments: Insights from aggregation behaviour and theoretical calculations
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Nanoplastics released into aquatic environments were found to be highly stable and resist aggregation and settling under many conditions, meaning they can persist and disperse widely rather than quickly sinking. This environmental stability makes nanoplastics particularly concerning as long-lived and mobile contaminants in water systems.
Photoaging-induced variations in heteroaggregation of nanoplastics and suspended sediments in aquatic environments: A case study on nanopolystyrene
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Researchers investigated how photoaging affects the aggregation behavior of polystyrene nanoplastics with suspended sediments in water. They found that 30 days of photoaging retarded aggregation in sodium chloride solutions due to steric hindrance from leached organic matter, but promoted aggregation in calcium chloride solutions through calcium bridging of newly formed oxygen-containing surface groups. The study provides mechanistic insights into how environmental weathering changes the transport and fate of nanoplastics in aquatic systems.
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