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A systematic review on the aging of microplastics and the effects of typical factors in various environmental media
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This review details how physical, chemical, and biological aging processes transform microplastics in aquatic environments, altering their surface properties, pollutant adsorption capacity, and ability to leach plasticizers and flame retardants. Aged microplastics pose compounded risks to aquatic organisms and human health by acting as more potent carriers of toxic chemicals and penetrating biological tissues more readily than pristine particles.
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Researchers modeled the chemical and hydrolytic aging of polyamide 6 in seawater using a new kinetic model that tracks chain scission and embrittlement, identifying the ductile-to-brittle transition as the physical threshold for microplastic fragment formation, while DNA metabarcoding revealed that bacterial communities colonizing the polymer surface shift distinctly depending on polymer type and weathering state.
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