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Estimation of Physico-Chemical and Heavy Metals in the Lakes of Grovnes & Broknes Peninsula, Larsemann Hill, East Antarctica

Chemistry Africa 2023 23 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count.
Laxmi Kant Bhardwaj, Sandeep Sharma, Tanu Jindal

Summary

Researchers measured physicochemical parameters and heavy metal concentrations in Antarctic lake waters during a scientific expedition, finding most values within acceptable limits but with some elevated TDS and phosphorus levels linked to local human activity. While focused on general water quality rather than microplastics specifically, this baseline characterization of a remote polar environment provides context for tracking emerging plastic contaminants in pristine regions increasingly affected by human presence.

Anthropogenic activity in Antarctica has increased due to the various scientific expeditions and tourism. Lake water sampling was carried out during the 34th Indian Scientific Expedition to Antarctica (ISEA) in the austral summer of 2014–2015. A total of 60 samples were collected from Grovnes & Broknes peninsula, Larsemann Hill, East Antarctica. The aim of this study was to investigate the physico-chemical parameters such as pH, total dissolved solids (TDS), electrical conductivity (EC), chloride (Cl−), total hardness (TH), nitrate (NO3−), nitrite (NO2−), phosphorus (P), sulphate (SO4−−), cyanide (CN−), chlorine (Cl), sulphide (S−−), and heavy metals like Al, Fe, Mn, Zn, Cu, Ni, and Cr in the collected samples. We also analysed indices like the potential ecological risk factor (Er) and potential ecological risk index (RI). We found pH (6.33–7.10), TDS (26.33–1128.0 mg/l), EC (0.06–2.25 μS/cm), Cl− (5.09–117.07 mg/l), TH (10.18–122.16 mg/l), NO3− (0.02–0.61 mg/l), NO2− (0.02–1.32 mg/l), P (0.29–3.27 mg/l), SO4−− (1.08–10.15 mg/l), CN− (0.01–0.26 mg/l), Cl (0.06–2.17 mg/l), S−− (0.01–0.84 mg/l), Al (0.01–0.79 µg/l), Fe (0.01–3.27 µg/l), Mn (0.14–12.83 µg/l), Zn (0.07–2.44 µg/l), Cu (0.01–5.37 µg/l), Ni (0.02–0.60 µg/l), and Cr (0.01–0.82 µg/l) in different ranges. We conclude that most of the parameters were found within the limits set by IS:10500 except some parameters like TDS was found higher in L6 NG, L7A NG, L7B NG, L1 SG, & L4 SG; Cl was found higher in L1E NG, P2 B, P3 B, P4 B, & Reid B; CN− was found higher in P2 B, & P4 B; S— was found higher in P2 B, P3 B, P4 B, & Reid B. In the future, the presence of new emerging pollutants like microplastics, and phthalate must be analysed in order to comprehensively assess the scale of environmental pollution in Antarctica.

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