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Spectral Classification of Large-Scale Blended (Micro)Plastics Using FT-IR Raw Spectra and Image-Based Machine Learning
Summary
Researchers developed and compared four machine learning classifiers for identifying microplastic types from Fourier transform infrared spectroscopy data using large-scale blended plastic datasets. The study found that a 1D convolutional neural network achieved the best overall accuracy at over 97%, outperforming decision tree and random forest models, offering a scalable alternative to traditional library-search methods for microplastic identification.
Microplastics (MPs) are currently recognized as emerging pollutants; their identification and classification are therefore essential during their monitoring and management. In contrast to most studies based on small datasets and library searches, this study developed and compared four machine learning-based classifiers and two large-scale blended plastic datasets, where a 1D convolutional neural network (CNN), decision tree, and random forest (RF) were fed with raw spectral data from Fourier transform infrared spectroscopy, while a 2D CNN used the corresponding spectral images as the input. With an overall accuracy of 96.43% on a small dataset and 97.44% on a large dataset, the 1D CNN outperformed other models. The 1D CNN was the best at predicting environment samples, while the RF was the most robust with less spectral data. Overall, RF and 2D CNNs might be evaluated for plastic identification with fewer spectral data; however, 1D CNNs were thought to be the most effective with sufficient spectral data. Accordingly, an open-source MP spectroscopic analysis tool was developed to facilitate a quick and accurate analysis of existing MP samples.
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