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Light‐Driven MXene‐Based Microrobots: Mineralization of Bisphenol A to CO2 and H2O

Small Methods 2023 23 citations

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Light-driven MXene-based microrobots functionalized with iron oxide and bismuth nanoparticles degraded approximately 60% of bisphenol A within 10 minutes and achieved near-complete removal within 1 hour, with over 86% of BPA fully mineralized to CO2 and water.

Light-driven magnetic MXene-based microrobots (MXeBOTs) have been developed as an active motile platform for efficiently removing and degrading bisphenol A (BPA). Light-driven MXeBOTs are facilitated with the second control engine, i.e., embedded Fe2 O3 nanoparticles (NPs) for magnetic propulsion. The grafted bismuth NPs act as cocatalysts. The effect of the BPA concentration and the chemical composition of the swimming environment on the stability and reusability of the MXeBOTs are studied. The MAXBOTs, a developed motile water remediation platform, demonstrate the ability to remove/degrade approximately 60% of BPA within just 10 min and achieve near-complete removal/degradation (≈100%) within 1 h. Above 86% of BPA is mineralized within 1 h. The photocatalytic degradation of BPA using Bi/Fe/MXeBOTs demonstrates a significant advantage in the mineralization of BPA to CO2 and H2 O.

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