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Porous carbon tubes from recycling waste COVID-19 masks for optimization of 8 mol% Y2O3-doped tetragonal zirconia polycrystalline nanopowder

Materials Today Chemistry 2023 9 citations

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Researchers carbonized waste polypropylene face masks with KOH activation to produce porous carbon tubes with surface areas exceeding 1,220 m²/g, then used these tubes as dispersants during ceramic nanopowder synthesis, yielding finer and more uniform zirconia particles than conventional activated carbon.

Polymers

Disposable polypropylene medical masks are widely used to protect people from injury caused by COVID-19 worldwide. However, disposable medical masks are non-biodegradable materials, and the accumulation of waste masks can pollute the environment and waste resources without a reasonable recycling method. The aims of this study are to transform waste masks into carbon materials and to use them as a dispersant in preparing high-quality 8 mol% YO-doped tetragonal zirconia nanopowders. The waste masks were carbonized to get a carbon source in the first step, then KOH was used to etch the carbon source creating a micropores structure in the carbon material after the carbon-bed heat treatment method. The resulting carbon material is a porous tube structure with a high specific surface area (1220.34 m/g) and adsorption capacity. The as-obtained porous carbon tubes were applied as a dispersant to produce 8 mol% YO-doped tetragonal zirconia nanopowders, and the resulting nanopowders owned well-dispersed and had the smallest particle size than that prepared by activated carbon as a dispersant. Besides, the sintered 8 mol% YO-doped tetragonal zirconia ceramic possessed high density, which resulted in higher ionic conductivity. These findings suggest that waste face masks can be recycled to prepare high-added-value carbon materials and provide a green and low-cost method to reuse polypropylene waste materials.

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